TROUBLESHOOTING GUIDE

Recommendation To Treated Type

Type of Treatment for ALPASTE

A Treated ALPASTE

Type Treatment Function
F Type Polymer coating Chemical resistance,
W Type Treatment by inhibiter Water borne metallic Paint

B Unique ALPASTE

Type Treatment Function
D Type Deodorized Printing ink
PCF Type Resin coated flake Powder Coating
Dry flake Aluminium Flake Powder ALC, Slurry Explosive, Plastic coloring
Solvent changed Type Base solvent exchange Printing ink, Marine, Plastic coloring

C Alloy Paste

Type Treatment Function
RFA Type Stain less Paste Exterior (chemical resistance)

Treated ALPASTE and its property

Treatment Non treated Resin coating
Type FX FZ
Color appearance
Resistance to peeling ×
Electrostatic property addition ×
Chemical
resistance
Acid
Alkali ×

Improvement of Adhesion & Peeling-proof

When being used to the plastic coating with 1-coat, ALPASTE may cause the poor adhesive problem, which is resulted in the poor scotch tape peeling test, by being affected by fatty acid on the aluminium flake surface. (No problem happens in the case of 2-coat film in which a clear-coat is applied.)
It is effective to prevent such problem to use the treated grades mentioned as below:

Resin coated flake (FX or FZ type):Coated with acrylic resin

Electrostatic Property

When the high voltage is applied to the metallic paint the oxidized film and fatty acid covering the aluminium pigments may cause the dielectric breakdown by being applied with high voltage, and the aluminium pigments are connected just like a conductor and let the electric current go to the earth side. Then the voltage cannot be applied to the paint for electrostatic coating.
The following processed grades are effective to prevent the said problem.

Resin coated flake (FX or FZ type):Coated with acrylic resin

Chemical Resistance ( resistance to acid / alkali )

It is recommendable to use resin coated ALPASTE, which is uniformly coated with special polymer on the aluminium flake surface, for chemical resistant application.

Resin coated flake (FX or FZ type etc.) (There are some grades depending on the required application)
Paint/ink for plastic coating / Plastic coloring Other general paint (It is also effective to improve adhesion and electrostatic property.)

Water borne ( Gas evolution )

Aluminium is well known as an amphoteric metal and generate the hydrogen gas by reaction with water at both pH areas, shown as below:

Acidic area: 2Al + 6H+ 2Al3+ + 3H2
Alkaline area: 2Al + 2OH- + 2H2O 2AlO2- + 6H2
The oleic acid or stearic acid used as the milling agent of aluminium paste is thought to be absorbed on -OH and -O of the oxidized film of aluminium surface. But the fatty acid film is apt to be removed in the presence of water, and the surface oxidized film is too thin to prevent from reaction with water.

There are three typical measures to treat the aluminium flake surface so as to give it the water resistance:

  • Treatment with inorganic compound (WJ, WX treatment,etc.)
  • Treatment with organic compound (WE, WB treatment,etc.)
  • Treatment in the paint manufacturing process

The stability and effect of the treatment to aluminium flake surface largely depend on the composition of binder to be dispersed and the pH area to be used.